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Hexavalent Chromium; The New OSHA Rule

 

Recently OSHA passed the Hexavalent Chromium Rule (29 CFR 1910.1026).  This rule went into effect in February of 2006.  All employers with greater than 20 employees were required  to comply with all requirements except for engineering controls by November of 2006 and all employers with less than 19 employees are required to comply with all requirements except for engineering controls by May 30 of 2007.  By May 31 of 2010 all employers are required to comply with all facets of the standard.

This rule covers all exposures to Hexavalent Chromium (Cr(VI)) except for applications as pesticides and exposures to Portland Cement.  In addition, when an employer can demonstrate, with the use of objective air monitoring data, that the product or activity involving Cr(VI) will not, under any conditions,  release Cr(VI) in concentrations at or above 0.5ug/m3 for an 8-hour time weighted average, the requirements of the rule do not apply.  However, in all other instances the rule does apply.  Compliance with the rule includes a number of requirements including  engineering controls, personal protective equipment, worker training, exposure monitoring and medical monitoring of employees.

Chromium and its compounds are utilized in a variety of manufacturing products such as  pigments, wood preservatives, stainless steel, textile dyes, leather tanning produces, and anti- corrosion coatings and plating products.  Employees can inhale airborne hexavalent chromium as a dust, fume or mist during production of these products; when working near chrome electroplating processes; during welding and hot-working with stainless steel, high chrome alloys and chrome-coated metal; and when applying and removing chromate-containing paints and other surface coatings.  Skin exposure can also occur during direct handling of solutions, coatings and cements that contain hexavalent chromium. 

Exposure to Cr(VI) is dangerous because it can cause many ailments such as, skin irritation, ulceration, and allergic dermatitis; nasal perforations, rhinitis, nosebleed, respiratory tract inflamation and irritation, occupational asthma, and pulmonary congestion and edema; eye irritation and damage; perforated eardrums; kidney and liver damage; gastric pain; erosion and discoloration of the teeth; and cancers of the lung, nasal passages and sinuses.1,2  The National Institute of Occupational Safety and Health considers all Cr(VI) compounds to be potential occupational carcinogens.2

Often the Material Safety Data Sheet will list one of the following compounds; Strontium Chromate, Calcium Chromate, Barium Chromate, Lead Chromate, Zinc Chromate, Ammonium Dichromate, Chromium Trioxide, Potassium Chromate, Potassium Dichromate, and Sodium Chromate as an ingredient in a product being used to indicate potential chromate exposure.  However, there are instances where potential Chromate exposure is not so obvious.  For example, during heavy MIG welding of mild steel using straight CO2 as the shield gas, concentrations of Cr(VI) ranging from 0.3 ug/m3 to 1.0 ug/m3 have been released.  Because of this, parts of the OSHA rule are applicable.  It has been reported that switching the shield gas from straight CO2 to a mixture of 75% Argon and 25% CO2 will reduce the amount of Cr(VI) emitted to below 0.06 ug/m3 and allow an exclusion from the requirements of the OSHA standard3

 

It is important that you be aware of the facts and requirements of the standard and the different job functions that may be regulated under this standard.  It is also important to understand what aspects of this standard apply to your business and your employees.   For further information about what this standard might mean for your business contact the professionals at EHI.  Our professionals are fully versed in all aspects of exposure assessment, air monitoring, and OSHA compliance programs and are available to assist you meet these new requirements.

 

References: 

1.            OSHA Fact Sheet, Health Effects of Hexavalent Chromium

2.            NIOSH, Safety and Health Topic: Hexavalent Chromium 

3.               Presentation by Edward Struber, CIH, Galson Laboratories, Chromium VI Current Monitoring Issues.  Presentation given during AIHA Northeast Conference, December 1, 2006.

4.            Small Entity Compliance Guide for the Hexavalent Chromium Standards. OSHA Publication 3320, (2006).

 

Environmental Health Investigations, Inc.

655 West Shore Trail
Sparta NJ 07871
Phone: 973-729-5649
E-mail: info@ehi-inc.com